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Last post 4 years ago by Tittums. 49 replies replies.
A little help?
Tittums Offline
#1 Posted:
Joined: 04-15-2019
Posts: 524
I wasn't sure if this was going to qualify for "cigar related" so I went ahead and posted here. I currently have a mix of multiple salts and salt+sucrose mixture that is in the 69-70% range and 68-70% range respectively. With these mixes locked down I moved on to testing the water vapor transfer rate (WVTR) of various air pillows we all get in our packages and am running into an unexpected issue with these.

Long story short, I was hoping someone with a hygrometer, these air pillows and a food-saver (for sealing) could try the same experiment with me. As you can see in the picture it is not going above 70-71% despite it being filled with normal tap water. To be this is very confusing because I was expecting high 80s to 90s since there is only water.

All I did was cut open the air pillow, filled it with water, then sealed it with my food saver and placed it in a ziplock with 3 hygrometers. The RH was around 58% before placing it inside (yes, my house has high humidity, it is florida) and after 12 hours it has not gone over 71% RH.
20191215_121202.jpg
dstieger Offline
#2 Posted:
Joined: 06-22-2007
Posts: 10,889
Wrong forum, nerd.....I mean, noob

Are you trying to learn something? Or just playing? What is it you want to know?

Paging Mr. jtokash
KingoftheCove Offline
#3 Posted:
Joined: 10-08-2011
Posts: 7,631
The confabulated distiller cone in your hygrometer is picking up a positive ionic charge from the sucrose, which is isolating the negative electrode on the RH sensor.
Use raw cane sugar, and it should work.
jespear Offline
#4 Posted:
Joined: 03-19-2004
Posts: 9,464
Way too much work, (well, for ME, anyway).
I just use the Heartfelt Beads, and I'm good to go.
dstieger Offline
#5 Posted:
Joined: 06-22-2007
Posts: 10,889
Wait...what....

When I read this earlier..well, skimmed, really....I thought you were talking about the humicare pillows...and still thought it a bit crazy. But, as I reread....you are doing some kind of testing experimenting with water in packing air pillows? What?

KingoftheCove Offline
#6 Posted:
Joined: 10-08-2011
Posts: 7,631
dstieger wrote:
Wait...what....

When I read this earlier..well, skimmed, really....I thought you were talking about the humicare pillows...and still thought it a bit crazy. But, as I reread....you are doing some kind of testing experimenting with water in packing air pillows? What?


Yeah, like I said..........cane sugar.
Tittums Offline
#7 Posted:
Joined: 04-15-2019
Posts: 524
KingoftheCove wrote:
The confabulated distiller cone in your hygrometer is picking up a positive ionic charge from the sucrose, which is isolating the negative electrode on the RH sensor.
Use raw cane sugar, and it should work.


I don't plan on using a salt+sugar solution for this and right now there is only distilled water in the testing bag so I am confused why it's stuck at 70-71%.

dstieger wrote:
Wait...what....

When I read this earlier..well, skimmed, really....I thought you were talking about the humicare pillows...and still thought it a bit crazy. But, as I reread....you are doing some kind of testing experimenting with water in packing air pillows? What?



Yes, that is exactly it. Long story short, DIY Boveda packs. But the plastic air pillows I have been using all stop releasing once the environment reaches 71%. Since there is nothing but distilled water in these air pillows I am confused as to why it is getting stuck at 71%.

Basically, if anyone is bored, interested in testing this, keep their air pillows on hand, and have a food saver to seal water in them I was curious if they could get higher than 71% with nothing but distilled water in the sealed pillow. I am just trying to find a proper package for the salt solution at this point. Once I figure that out I will post my results and solutions then ask for suggestions on lower RH packs to work on.
KingoftheCove Offline
#8 Posted:
Joined: 10-08-2011
Posts: 7,631
Tittums wrote:
I don't plan on using a salt+sugar solution for this and right now there is only distilled water in the testing bag so I am confused why it's stuck at 70-71%.


Just talkin chit dude.
Making your own Bovedas?
Good for you! They’re just cheap enough, and easy enough to maintain and recharge, for me to not bother with trying to make my own.
Good luck in your quest.
Tittums Offline
#9 Posted:
Joined: 04-15-2019
Posts: 524
KingoftheCove wrote:
Just talkin chit dude.
Making your own Bovedas?
Good for you! They’re just cheap enough, and easy enough to maintain and recharge, for me to not bother with trying to make my own.
Good luck in your quest.


I figured, and yeah they are cheap but I am stubborn. I look at $40 for a brick of 12 and go "I can buy the salts in them for less than that and make more than 12 67 gram packs".
victor809 Offline
#10 Posted:
Joined: 10-14-2011
Posts: 23,866
I'm honestly surprised the plastic pillows release that much moisture. Are you sure you aren't getting an increase to 71% from droplets of water on the outside (contamination from filling/sealing)?

Further, if in fact you are getting a real result here (sufficient water vapor escaping the pillows to raise humidity from 58% to 71%) then you would almost want to call the experiment a success. You don't intend to keep your cigars above 65% (I hope), so you will have to put some mixture into the pillows which will slow your water vapor release to ensure you don't over humidify.

The bigger problem would be going the other way. How will you remove humidity from the humidor if it goes over?
Tittums Offline
#11 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
I'm honestly surprised the plastic pillows release that much moisture. Are you sure you aren't getting an increase to 71% from droplets of water on the outside (contamination from filling/sealing)?

Further, if in fact you are getting a real result here (sufficient water vapor escaping the pillows to raise humidity from 58% to 71%) then you would almost want to call the experiment a success. You don't intend to keep your cigars above 65% (I hope), so you will have to put some mixture into the pillows which will slow your water vapor release to ensure you don't over humidify.

The bigger problem would be going the other way. How will you remove humidity from the humidor if it goes over?


I dried the bag after sealing then let it sit for an hour before putting it in the bag so there shouldn't be contamination.

I am not sure of the applications for higher than 70% but I am annoyed that it is not going much higher than that when there is only water present. I believe above 70% is for seasoning and instruments?

As for two-way, these should be two-way but I have not tested. Quoting from one of Boveda's patents:

Typical films that meet the requirements of the present invention include food wrap films of
polyvinylchloride, microfiberous polyethylene (TYVEK® from Dupont), Hytrel® (DuPont), microporous
polyethylene, high density polyethylene, oriented polystyrene, cellophane, polycarbonate, and the
like that have WVTR of 3 grams or more.


Hytrel has been used in all their patents (from what they claim in them) but I cannot find this stuff in small amounts so I am working with the air pillows which at least one of them is inked with HDPE.+

Ultimately, I would like to get my salt solution packaged in something that releases (and pulls moisture out of the air) faster than these are. I am going to test an actual boveda to see how quickly it brings things up to ambient later today.

And just as I checked things to pull a graph for you things are up to 72%

If you look at the graph, it doesn't seem to be releasing moisture fast enough, or I am expecting it to be faster when it does not need to be? https://i.imgur.com/eDwbZC1.jpg
victor809 Offline
#12 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
I dried the bag after sealing then let it sit for an hour before putting it in the bag so there shouldn't be contamination.

I am not sure of the applications for higher than 70% but I am annoyed that it is not going much higher than that when there is only water present. I believe above 70% is for seasoning and instruments?

As for two-way, these should be two-way but I have not tested. Quoting from one of Boveda's patents:

Typical films that meet the requirements of the present invention include food wrap films of
polyvinylchloride, microfiberous polyethylene (TYVEK® from Dupont), Hytrel® (DuPont), microporous
polyethylene, high density polyethylene, oriented polystyrene, cellophane, polycarbonate, and the
like that have WVTR of 3 grams or more.


Hytrel has been used in all their patents (from what they claim in them) but I cannot find this stuff in small amounts so I am working with the air pillows which at least one of them is inked with HDPE.+

Ultimately, I would like to get my salt solution packaged in something that releases (and pulls moisture out of the air) faster than these are. I am going to test an actual boveda to see how quickly it brings things up to ambient later today.

And just as I checked things to pull a graph for you things are up to 72%

If you look at the graph, it doesn't seem to be releasing moisture fast enough, or I am expecting it to be faster when it does not need to be? https://i.imgur.com/eDwbZC1.jpg


That's a really good graph. It shows pretty clearly that what we are seeing isn't contamination, but instead release of the water vapor. That seems clear by the asymptotic nature of the graph. There is some RH in the bag at which the pressure of water vapor in the bag is equal to that across the membrane.

As to why we're tapped out at 70ish percent... let me look.
victor809 Offline
#13 Posted:
Joined: 10-14-2011
Posts: 23,866
I wonder if your inner bag is holding you back. You have a very large percentage of that volume made up of liquid water, that means that any vaporization of the water has to be done in a smaller space, leading to a lower concentration of gaseous water molecules. You're limited there by vapor pressure.

I would be curious if there is a difference if you were to try a second pillow, only like 1/3 full of water, but with air taking up the other 2/3. You might get a different top end.

Tittums Offline
#14 Posted:
Joined: 04-15-2019
Posts: 524
As for testing two-way, I should be able to leave a pillow with nothing but sodium chloride in it and a cup of water next to it for a few days, remove the water and things should be around 75%. My AC is crap as is my state so I am stuck at around 58% ambient in my home so there is room for the salt to absorb more moisture even if it is already contaminated by ambient humidity.
Tittums Offline
#15 Posted:
Joined: 04-15-2019
Posts: 524
So I guess I was wrong about it not releasing moisture fast enough. HDPE is viable as suggested in the patent.

Actual Boveda pack: https://i.imgur.com/eJvWMHA.jpg

With that done I am going to make a 50 gram pack with just sodium chloride in it weighed on my AWS-100 then put it in the test bag with a cup of water to see how much water it takes in over a few days. The AWS-100 is supposed to be accurate within 0.02 grams and it weights down to 0.01 so I will see even the slightest change.
tamapatom Offline
#16 Posted:
Joined: 03-19-2015
Posts: 7,381
I wonder if Victor's inner bag is holding him back..........
victor809 Offline
#17 Posted:
Joined: 10-14-2011
Posts: 23,866
...no .... It's the one on the outside. The one I married.

.... Oh.... Bag... I thought you said... Nevermind...
Tittums Offline
#18 Posted:
Joined: 04-15-2019
Posts: 524
So these air pillows only function one-way as far as vapor goes. I made a 50 gram pack with nothing but sodium chloride and it only gained 0.02 grams while in a ziplock with a cup of water (it was 90% humidity) after 24 hours. That is within the margin of error the AWS-100 has.

For now, I am going to use them as a one-way system since they still function as a barrier to the salts. I might try Tyvek at a later date since I can pick up envelopes made of that material at the post office but for the time being I am not sure where to get the Hytrel stuff Boveda uses.
gummy jones Offline
#19 Posted:
Joined: 07-06-2015
Posts: 7,969
I find romaine is superior to iceberg
Tittums Offline
#20 Posted:
Joined: 04-15-2019
Posts: 524
gummy jones wrote:
I find romaine is superior to iceberg


My friend calls that salmonella lettuce since it is constantly getting recalled. I do agree about it being superior though.
victor809 Offline
#21 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
So these air pillows only function one-way as far as vapor goes. I made a 50 gram pack with nothing but sodium chloride and it only gained 0.02 grams while in a ziplock with a cup of water (it was 90% humidity) after 24 hours. That is within the margin of error the AWS-100 has.

For now, I am going to use them as a one-way system since they still function as a barrier to the salts. I might try Tyvek at a later date since I can pick up envelopes made of that material at the post office but for the time being I am not sure where to get the Hytrel stuff Boveda uses.


I'm curious how it could be 1-way only. Especially since it's designed to hold air inside.
did you try two with varying volumes of water and air?

If you really truly believe it's a 1-way only system, maybe turn one inside out and test it?
Tittums Offline
#22 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
I'm curious how it could be 1-way only. Especially since it's designed to hold air inside.
did you try two with varying volumes of water and air?

If you really truly believe it's a 1-way only system, maybe turn one inside out and test it?


Well, the idea is to create boveda for cheaper than what they cost. If it's only one-way (inside or out) it's not boveda. For my needs to I don't need two-way if it's only going to be a set RH. I can just air out my humidor for incoming cigars that are over humidified. I have been having to do that anyway because even some 5 packs I bought caused my humidity to jump.
victor809 Offline
#23 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
Well, the idea is to create boveda for cheaper than what they cost. If it's only one-way (inside or out) it's not boveda. For my needs to I don't need two-way if it's only going to be a set RH. I can just air out my humidor for incoming cigars that are over humidified. I have been having to do that anyway because even some 5 packs I bought caused my humidity to jump.


I'm asking more for curiosity sake, to prove the theory.
If you turn it inside out and still cannot get the salt to absorb moisture, then we need to re-think how the experiment is set up.
Tittums Offline
#24 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
I'm asking more for curiosity sake, to prove the theory.
If you turn it inside out and still cannot get the salt to absorb moisture, then we need to re-think how the experiment is set up.


I just put an inflated pillow in a glass of water and am using the 100G weight that came with my scale to calibrate it to force it partially underwater. I can't test reversing it at the moment as my hygrometers are in use testing different salt mixes.

Since it is been challenging me the most I am currently going back to using Ammonium Chloride since it is 80% RH but is used in 65% and 69% Bovedas and I can't seem to get it below 72%. Currently playing around with the 65% ingredients:

Quote:

Water (Reverse Osmosis) 7732-18-5 50 to 67
Sodium chloride 7647-14-5 8 to 13
Ammonium Chloride 12125-02-9 13 to 33
Glycerin 56-81-5 10 to 29
Xanthan gum 11138-66-2 0.5 to 1.0
Citric acid 77-92-9 0.01 to 0.5
dstieger Offline
#25 Posted:
Joined: 06-22-2007
Posts: 10,889
After you solve that, I have another one for you, titts.

Scientifically 'prove' how storage temperature is related to relative humidity -- not just some meterology class regurgitation, but how the temp/humidity/RH relationship is manifested in rolled tobacco leaves, also. Every time someone convinced me they were on the right track, a better argument deflated them.
victor809 Offline
#26 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
I just put an inflated pillow in a glass of water and am using the 100G weight that came with my scale to calibrate it to force it partially underwater. I can't test reversing it at the moment as my hygrometers are in use testing different salt mixes.

Since it is been challenging me the most I am currently going back to using Ammonium Chloride since it is 80% RH but is used in 65% and 69% Bovedas and I can't seem to get it below 72%. Currently playing around with the 65% ingredients:



Interesting. Well, if you're using NH4Cl solution in water inside a plastic bag that should be ok, as long as it stays sealed.
Looks like with a very small amount of heat you can get some off-gassing of ammonia (as well as creation of a tiny bit of HCl which is supposed to be a gas, but I'd bet would just acidify your water a little)...

If the bag will pass water vapor, it may also pass NH4, which means you may get a small ammonia odor in your humidor.
USNGunner Offline
#27 Posted:
Joined: 05-17-2019
Posts: 4,402
dstieger wrote:
After you solve that, I have another one for you, titts.

Scientifically 'prove' how storage temperature is related to relative humidity -- not just some meterology class regurgitation, but how the temp/humidity/RH relationship is manifested in rolled tobacco leaves, also. Every time someone convinced me they were on the right track, a better argument deflated them.



LOL. Damned scientists. "If there is concurrence, there is no science."
victor809 Offline
#28 Posted:
Joined: 10-14-2011
Posts: 23,866
dstieger wrote:
After you solve that, I have another one for you, titts.

Scientifically 'prove' how storage temperature is related to relative humidity -- not just some meterology class regurgitation, but how the temp/humidity/RH relationship is manifested in rolled tobacco leaves, also. Every time someone convinced me they were on the right track, a better argument deflated them.


.... that's all about exactly how much moisture is in the air. Which is a relationship between temperature (because at different temperatures more or less water can be "dissolved" in the air) and the amount of water present.

This is pretty well established science (outside of your strange statement about how it would "manifest in rolled tobacco leaves") so I'm not sure how anyone would deflate the argument.
dstieger Offline
#29 Posted:
Joined: 06-22-2007
Posts: 10,889
So, I guess the practical question is something like this:

If I like my cigars that come out of my living room humidor that has a hygrometer reading 63%RH and 69 degrees.....

should I keep the humidor in my garage which is right around 48 degrees currently, at 63%, also?

Tittums Offline
#30 Posted:
Joined: 04-15-2019
Posts: 524
dstieger wrote:
After you solve that, I have another one for you, titts.

Scientifically 'prove' how storage temperature is related to relative humidity -- not just some meterology class regurgitation, but how the temp/humidity/RH relationship is manifested in rolled tobacco leaves, also. Every time someone convinced me they were on the right track, a better argument deflated them.


I've only been in this hobby for a year (next feb) but my basic understanding of RH/Temp is no higher than 70F to prevent tobacco beetles then you want a custom RH/Temp that is going to result in the best smoke once it leaves your humidor.

Based one what I have seen for humid locations like Florida (where I live) you want things at around 64% and 64-66F since you are pulling the cigar out of a cooler environment that shock is going to pull humidity out of the air. This is purely observation on my part and I honestly am clueless if it is accurate.

Humidity control is my obsession at the moment so I don't really think or care about temperature. One thing to do keep in mind if you are using a humidity control solution that involves salts (Bovedas, and the other brands that are popping up like RH Shield and Schmécké) is temperature will have an effect on how much moisture the salts will release but this is usually only a difference of 1-2%.

I am not sure how the mods feel about linking PDFs due to their exploitable nature so I will include a screenshot from one I have referenced often: https://i.imgur.com/NjjV2Zb.png If you want the full paper google "Humidity fixed points of binary saturated aqueous"

The two salts Boveda uses most are Ammonium Chloride and Sodium Chloride, these are 1% or even less than 1% RH difference between 0C and 20C which is excellent since we're in a narrower 16C-21C (60F-69.8F) window. Since Ammonium Chloride was not listed in the screenshot I'll provide it here: https://i.imgur.com/YclKuEw.png


Tittums Offline
#31 Posted:
Joined: 04-15-2019
Posts: 524
dstieger wrote:
So, I guess the practical question is something like this:

If I like my cigars that come out of my living room humidor that has a hygrometer reading 63%RH and 69 degrees.....

should I keep the humidor in my garage which is right around 48 degrees currently, at 63%, also?



Like I said in my previous reply I am no expert here but I would actually suggest a higher RH of 1-2% if you are going to be smoking it in 48F. The cold (which everyone should know because this is why you should never store cigars in a refridgerator) will suck humidity right out of anything. And sure, you are going to light it and that will be a source of heat but you are hopefully trying to keep the point between you and the fire cool since as we all know that will affect flavor.

In short, if you are pulling it from a warm environment into a cold environment you want a slightly higher RH as storage since this is going to give you a buffer to lose humidity.

In reverse, a cold to a hot environment, you want a slightly lower RH because that cold stick is going to suck humidity out of the air.

Depending on the extremes its not going to be a huge amount of humidity transfer but that buffer should improve your smoke experience.
victor809 Offline
#32 Posted:
Joined: 10-14-2011
Posts: 23,866
dstieger wrote:
So, I guess the practical question is something like this:

If I like my cigars that come out of my living room humidor that has a hygrometer reading 63%RH and 69 degrees.....

should I keep the humidor in my garage which is right around 48 degrees currently, at 63%, also?



No.

There's a chart called a psychrometric chart which is a pain in the ass but I've had to use in the past. It shows you the relationship between temperature and relative humidity.
If you follow a psychrometric chart to see the "grains of water" (this is a measure of the amount of water) in the air at 48F and 63%rh, you will find that is much fewer grains than an equivalent 63%RH at 69F.

We can assume that the grains of water in the air will correlate directly with how much is available to be absorbed by the tobacco leaves
Tittums Offline
#33 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
No.

There's a chart called a psychrometric chart which is a pain in the ass but I've had to use in the past. It shows you the relationship between temperature and relative humidity.
If you follow a psychrometric chart to see the "grains of water" (this is a measure of the amount of water) in the air at 48F and 63%rh, you will find that is much fewer grains than an equivalent 63%RH at 69F.

We can assume that the grains of water in the air will correlate directly with how much is available to be absorbed by the tobacco leaves


Much better than my explanation, but this is where you show you are more educated on this than myself. "Grains of water" is not a term I am familiar with so I am guessing this is some scientific term to reference a fraction of a gram when refering to moisture or vaporized liquids.
victor809 Offline
#34 Posted:
Joined: 10-14-2011
Posts: 23,866
An easy way to look at RH is that at any given temperature 100% RH is when water vapor will start condensing. If you are at 60% RH and 70F, and you take that box and reduce the temperature to 50F, the amount of moisture already present as vapor will condense to water, because vapor cannot hold that much moisture at 50F (you can follow the psychrometric chart and see that 60% at 70F is greater than 100% at 50F.)

Now, once you open the box, the moisture will disappear, beccause the volume of your box is tiny compared to the volume of the garage, and your cigars will then be held in an environment with much less moisture than before
victor809 Offline
#35 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
Much better than my explanation, but this is where you show you are more educated on this than myself. "Grains of water" is not a term I am familiar with so I am guessing this is some scientific term to reference a fraction of a gram when refering to moisture or vaporized liquids.


honestly don't know where "grains" came from. I had never heard the term until I had to work on automation systems for building management systems in the pharma industry. These control the air handling units which have to remove (or add) moisture to the air for the manufacturing suites. People would get very obsessed about exactly how many grains of moisture were in the air before it was heated to the temperature of the manufacturing suite.

When I was in science I had never used the term "grains"... seems to be limited to people who care about climate control. Science uses grams (and the variations on that)
Tittums Offline
#36 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
honestly don't know where "grains" came from. I had never heard the term until I had to work on automation systems for building management systems in the pharma industry. These control the air handling units which have to remove (or add) moisture to the air for the manufacturing suites. People would get very obsessed about exactly how many grains of moisture were in the air before it was heated to the temperature of the manufacturing suite.

When I was in science I had never used the term "grains"... seems to be limited to people who care about climate control. Science uses grams (and the variations on that)


I can definitely understand that. I sometimes worry about how many miligrams 1 gram of sodium chloride is since I live in a humid climate so 1 gram of sodium chloride for me is not 100% sodium chloride unless I go to the trouble of dehydrating it (which I do not). This goes the same for a lot of drugs since they will also absorb moisture from the air. Depending on the drug, you can kill someone, or fail to help someone if 100miligram os something is too many miligrams of water from absorbtion.
victor809 Offline
#37 Posted:
Joined: 10-14-2011
Posts: 23,866
There is an issue with weighing, but the bigger problem in our case was that the drug was severely hygroscopic. Apparently if it wasn't maintained below a specific humidity it would absorb too much water, and this would lead to issues in properly blending it and pressing it. But yes, you are correct. If something absorbs water easily, then weighing it at two different RHs would give you two different concentrations of drug. Not something you want in medicine. I don't know if the values would be different enough to kill/not help someone, I don't think the tolerances are quite that close. But it would certainly wreck hell with any clinical trials trying to measure the patient's ability to process the drug.
Tittums Offline
#38 Posted:
Joined: 04-15-2019
Posts: 524
Any chemists in the house? Every time I play around with Ammonium Chloride and Sodium Chloride in a solution I always go above 70% RH. The question is (and google has failed me or I suck at googling) is there a reaction I am not getting between Citric Acid and the previously mentioned Chlorides?

Currently working with:

Test Batch 5 ():

*10.78 gram vessel*

3G Water
4G Ammonium Chloride
1G Sodium Chloride
3G Vegetable Glycerine

The 65% and 69% bovedas use Citric Acid and Citric Acid+Sodium Citrate respectively but it is always above 70%

tl;dr, at this point I am trying to use up my remaining Ammonium Chloride. I technically don't need this to work because I can easily get (my current target for this batch) of 64-65% with Sodium Chloride and Magnesium Chloride.

For reference at 20c/68F these salts have the following RH in solution:

Sodium Chloride: 75%
Ammonium Chloride: 80% (this is what makes me say it makes no sense to use it for lower than 75% RH)
Magnesium Chloride: 33%

Reference Data: https://i.imgur.com/witoLbu.png
victor809 Offline
#39 Posted:
Joined: 10-14-2011
Posts: 23,866
Best guess ... in equilibrium you may have a little bit of ammonia being formed.

With heat NH4Cl will form a bit of this:
NH4Cl → NH3 + HCl

Additionally, we also know
NH4Cl + NaOH → NH3 + NaCl + H2O

So, if we assume that at equilibrium some percentage of both sides of these reactions will be represented, then it is likely some of the NH3 formed in the second reaction is reacting with the NaCl and H2O already present to re-form NH4Cl and also create NaOH.

Throw in the additional presence of MgCl2... which may be forming an equilibrium with the NaOH as well... which will create Mg(OH)2 as well.

Sh1t.... I'm way too far removed from my undergrad chemistry to start mapping this all out. Needless to say, you may be forming some compounds you aren't expecting here....
Tittums Offline
#40 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
Best guess ... in equilibrium you may have a little bit of ammonia being formed.

With heat NH4Cl will form a bit of this:
NH4Cl → NH3 + HCl

Additionally, we also know
NH4Cl + NaOH → NH3 + NaCl + H2O

So, if we assume that at equilibrium some percentage of both sides of these reactions will be represented, then it is likely some of the NH3 formed in the second reaction is reacting with the NaCl and H2O already present to re-form NH4Cl and also create NaOH.

Throw in the additional presence of MgCl2... which may be forming an equilibrium with the NaOH as well... which will create Mg(OH)2 as well.

Sh1t.... I'm way too far removed from my undergrad chemistry to start mapping this all out. Needless to say, you may be forming some compounds you aren't expecting here....



Yeah, I am definitely trying to avoid HCl since I believe that is lethal? So I have not started heating things and will likely avoid buying a boiling flask to start doing it.

NaOH is Sodium Hydroxide? Unless I made it by accident this shouldn't be present?

MgCl2 is not in this solution but I am willing to accept some contamination from previous mixes if the salts managed to form within the bag itself while evaporating.

I am just bummed about this because I didn't spend too much on the Ammonium Chloride but the smallest amount I could get on Amazon was 1 pound so I have a lot of it.

As I write this I remember it has uses in food preparation which provided more information upon searching:

Quote:
It has low hygroscopicity, but it can also absorb moisture and agglomerate in wet and rainy weather. Powdered food grade Ammonium Chloride is very easy to absorb moisture, especially wet Ammonium; the moisture absorption point is generally around 76%


Again, no expert here, but maybe I am adding too much water?

edit: After looking into NaOH more I don't believe I would have made or even willingly be involved with it since it causes burns to the skin. I believe all of Boveda's stuff is designed around the idea a child or pet might get into it and it is reletively non-toxic. While I do not have kids, I do have German Shepherds so what I am making for personal use I am trying to make it non-toxic.
victor809 Offline
#41 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
Yeah, I am definitely trying to avoid HCl since I believe that is lethal? So I have not started heating things and will likely avoid buying a boiling flask to start doing it.

NaOH is Sodium Hydroxide? Unless I made it by accident this shouldn't be present?

most equations are reversible, and at equilibrium (equilibrium is based on the concentrations of everything present) you'll get a bit from each side of the arrow. If you look at the equations above, NH3, NaCl and H2O are all that's required for the equation to move right to left to give you NaOH.

I wouldn't worry about HCl being lethal. I'm betting it would just slightly change the pH of your water... and probably smell like a pool a little.
Quote:

MgCl2 is not in this solution but I am willing to accept some contamination from previous mixes if the salts managed to form within the bag itself while evaporating.
ignore that part of my statement. I misread your post above and thought you'd added MgCl2.
Quote:

I am just bummed about this because I didn't spend too much on the Ammonium Chloride but the smallest amount I could get on Amazon was 1 pound so I have a lot of it.

As I write this I remember it has uses in food preparation which provided more information upon searching:



Again, no expert here, but maybe I am adding too much water?


I am NOT good at figuring total solubility. but that's an easy thing to test.
Maybe first try mixing the dry components and then put them in a sealed container with an open tub of water. See how much it absorbs under those conditions. You probably will want to make sure you add less than that to your makeshift boveda, so that it has room to absorb.
victor809 Offline
#42 Posted:
Joined: 10-14-2011
Posts: 23,866
It's all in the dose.
A little NaOH (basic) and a little HCl are not dangerous, at low concentrations. And at these concentrations are probably in the food you eat.
Tittums Offline
#43 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:

Maybe first try mixing the dry components and then put them in a sealed container with an open tub of water. See how much it absorbs under those conditions. You probably will want to make sure you add less than that to your makeshift boveda, so that it has room to absorb.


I am tempted to try this next since I can't make it work in solution.

victor809 wrote:
It's all in the dose.
A little NaOH (basic) and a little HCl are not dangerous, at low concentrations. And at these concentrations are probably in the food you eat.


Forgive me if I am confusing things here (I am googling all of these since I do not know the abbreviations and periodic tables) but we're talking about hydrogen chloride (which would be in a gas state if heating)?

Quote:
Hydrogen chloride forms corrosive hydrochloric acid on contact with water found in body tissue. Inhalation of the fumes can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory system failure, and death. Skin contact can cause redness, pain, and severe skin burns. Hydrogen chloride may cause severe burns to the eye and permanent eye damage.


Not stuff I want to play with in any amount.
Tittums Offline
#44 Posted:
Joined: 04-15-2019
Posts: 524
Either way, I want to wrap my personal experiments up and start a "DIY Boveda (with caveats) thread. I am going to abandon the Ammonium Chloride for the time being and quickly figure out 2 batches of 65% that are (sodium chloride+sugar) and (sodium chloride+magnesium chloride). This should limit the requirements of DIYer's to:

1. Must have a food scale to measure things in grams.
2. Must have table salt and sugar OR:
3. Must have table salt and magnesium chloride (magnesium chloride being used in salt baths for aches and pains but also kid/pet friendly)
4. You buy cigars from cigarbid and have the air pillow packing materials used as a ONE WAY vapor barrier
5. Have a foodsaver or similar to seal these air pillows.

I got the 69-70% range covered with the above mentioned chemicals since 70% is what a lot of people obsess about even if its not recommended. Once I lock down 64-65% I will post the new thread and ask people to suggest different target RH for me to work on.

If people care enough, they can test the mixes in other packaging material and come up with other options. Something two-way would be preferred and I intend to get my hands on Tyvek and Hytrel once I stop spending so much money on cigars in the future (wonder if anyone stops spending money on cigars?).
victor809 Offline
#45 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:
I am tempted to try this next since I can't make it work in solution.
I would be interested in the results
Quote:

Forgive me if I am confusing things here (I am googling all of these since I do not know the abbreviations and periodic tables) but we're talking about hydrogen chloride (which would be in a gas state if heating)?

Not stuff I want to play with in any amount

Yes and no. Everything is in equilibrium. HCl gas becomes Hydrochloric Acid when it interacts with water vapor (which we'd assume there is plenty of). You'll probably recognize hydrochloric acid... that's the acid that's in your stomach. Again, at low concentrations it's harmless. We're dealing with very small amounts here. Heck, there is probably some HCl in gaseous form in the air you breathe at a pool that's chlorinated.

These are all at very low levels, way too low to be harmful.

However, I mention them because our sense of smell (and taste) are much more sensitive. And small amounts of ammonia or chlorine can impact cigar flavor much more I think than they can damage you.
Tittums Offline
#46 Posted:
Joined: 04-15-2019
Posts: 524
Tittums wrote:

Test Batch 5 ():

*10.78 gram vessel*

3G Water
4G Ammonium Chloride
1G Sodium Chloride
3G Vegetable Glycerine


I didn't bother with a new mix last night so this sat overnight and is now reading 63% oddly enough so I guess I am going to keep playing with it.

Tittums wrote:
I just put an inflated pillow in a glass of water and am using the 100G weight that came with my scale to calibrate it to force it partially underwater. I can't test reversing it at the moment as my hygrometers are in use testing different salt mixes.


This did not work, there is no water in the bag so I am going to try turning it inside out then sealing it and doing the same thing. If it were a Boveda it would be oversaturated with water.
victor809 Offline
#47 Posted:
Joined: 10-14-2011
Posts: 23,866
Tittums wrote:


This did not work, there is no water in the bag so I am going to try turning it inside out then sealing it and doing the same thing. If it were a Boveda it would be oversaturated with water.


I don't think this would work.

Water is not equal to water vapor

I wouldn't expect water in liquid form to pass through plastic (possibly not even through a boveda, although I don't know what that's made of exactly)... by submerging your plastic bag you are ensuring it isn't in any contact with water vapor at all, only liquid water.

Honestly, I wouldn't expect a lot of vapor transfer to an empty bag either, even if it's in a high humidity container. I would expect you would need some dessicant inside that bag to provide the difference in water vapor between the two sides
Tittums Offline
#48 Posted:
Joined: 04-15-2019
Posts: 524
victor809 wrote:
I don't think this would work.

Water is not equal to water vapor

I wouldn't expect water in liquid form to pass through plastic (possibly not even through a boveda, although I don't know what that's made of exactly)... by submerging your plastic bag you are ensuring it isn't in any contact with water vapor at all, only liquid water.

Honestly, I wouldn't expect a lot of vapor transfer to an empty bag either, even if it's in a high humidity container. I would expect you would need some dessicant inside that bag to provide the difference in water vapor between the two sides


Well I know you can oversaturate Boveda packs (I purposely dried one completely out then submerged it and it got way bigger and had to release a lot of water before it was releasing the set amount)

In their patents, they always reference Hytrel in their proof of concept for releasing the correct amount of humidity as well as absorbing excess humidity so that's the stuff I really want to test if I can find it in thin sheets.

See: https://www.dupont.com/products/hytrel.html
Tittums Offline
#49 Posted:
Joined: 04-15-2019
Posts: 524
Added 2 more grams of water to the current mix and its slowly up to 65 now and I think it will go over but I can bring that backdown. Despite 70% not being suggested some people consider it a silly gold standard so what should I focus on (for cigars) besides 70% and 65%?
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